太阳成8722(中国)有限公司-GREEN NO.1

标题：Shape-controlled nanostructured magnetite-type materials as highly efficient Fenton catalysts作者：Hou, Liwei; Zhang, Qinghua; Jerome, Francois; Duprez, Daniel; Zhang,Hui;Royer, Sebastien

来源出版物：APPLIED CATALYSIS B-ENVIRONMENTAL 卷：144页：739-749 DOI：10.1016/j.apcatb.2013.07.072 出版年：JAN 2014

摘要：Nanostructured Fe3O4 particles were obtained through hydrogen thermal reduction of alpha-Fe2O3 particles synthesized via an ionic liquid assisted hydrothermal process. The morphology and microstructure of the nano-sized Fe3O4 particles were characterized by using X-ray diffraction, N-2 physisorption, transmission electron microscopy, and temperature-programmed reduction. As-prepared magnetite samples show microcube, nanosphere, and porous nanorod morphologies. Activity of the nanostructures was evaluated for the Fenton reaction, using phenol as model molecule. While commercial Fe3O4 presents very limited activity, rod-type nanostructure exhibited exceptional activity toward phenol removal under mild conditions; 98% phenol was converted, and the total organic carbon (TOC) abatement was 74%. The reusability of porous nanorods of Fe3O4 was also investigated after three successive runs, which demonstrated the promising application of the catalyst in the oxidative degradation of organic pollutants. In addition, the material activity is strongly affected by the reduction degree, highlighting the beneficial effect of Fe-0/Fe3O4 mixed phase formation to achieve higher activity.

入藏号：WOS:000327686200086

文献类型：Article

语种：English

作者关键词：Fe3O4 Ionic liquid, Porous materials, Iron phase, Fenton

扩展关键词：IRON-OXIDE NANOPARTICLES; ZERO-VALENT IRON; FE3O4 NANOPARTICLES; ELECTRON-TRANSFER; SIZE-SELECTION; BISPHENOL-A; DEGRADATION; OXIDATION; REDUCTION; COMPOSITES

通讯作者地址：Royer, Sebastien ;Univ Poitiers, CNRS UMR 7285, IC2MP, 4 Rue Michel Brunet, F-86022 Poitiers, France.

电子邮件地址：eeng@whu.edu.cn; sebastien.royer@univ-poitiers.fr

地址：

[Hou, Liwei; Zhang, Hui] Wuhan Univ, Dept Environm Engn, Wuhan 430079, Peoples R China.

[Zhang, Qinghua; Jerome, Francois; Duprez, Daniel; Royer, Sebastien] Univ Poitiers, CNRS UMR 7285, IC2MP, F-86022 Poitiers, France.

研究方向：Chemistry; Engineering

ISSN：0926-3373